Mutagenicity of 2,4,6-trinitrotoluene-surfactant complexes.

Screening Effective Factors in Slurry Phase Bioremediation of 2,4,6-Trinitrotoluene (TNT) Contaminated Soil

Production of eight different hydride complexes and nitrite release from 2,4,6-trinitrotoluene by Yarrowia lipolytica.

2,4,6-Trinitrotoluene (TNT) transformation by the yeast strain Yarrowia lipolytica AN-L15 was shown to occur via two different pathways. Direct aromatic ring reduction was the predominant mechanism of TNT transformation, while nitro group reduction was observed to be a minor pathway. Although growth of Y. lipolytica AN-L15 was inhibited initially in the presence of TNT, TNT transformation was o...

Hazard characterization and identification of a former ammunition site using microarrays, bioassays, and chemical analysis.

More than 100,000 tons of 2,4,6-trinitrotoluene were produced at the former ammunition site Werk Tanne in Clausthal-Zellerfeld, Germany. The production of explosives and consequent detonation in approximately 1944 by the Allies caused great pollution in this area. Four soil samples and three water samples were taken from this site and characterized by applying chemical-analytical methods and se...

Ultrasensitive trace analysis for 2,4,6-trinitrotoluene using nano-dumbbell surface-enhanced Raman scattering hot spots.

We report an ultra-sensitive surface-enhanced Raman scattering (SERS)-based detection system for 2,4,6-trinitrotoluene (TNT) using nano-dumbbell structures formed by the electrostatic interaction between positively and negatively charged gold nanoparticles. First, Meisenheimer complexes were produced between TNT and l-cysteine on gold substrates, and 4-mercaptopyridine (4-MPY) labeled gold nano...

Proteomic Analysis of 2,4,6-Trinitrotoluene Degrading Yeast Yarrowia lipolytica

2,4,6-trinitrotoluene (TNT) is a common component of many explosives. The overproduction and extensive usage of TNT significantly contaminates the environment. TNT accumulates in soils and aquatic ecosystems and can primarily be destroyed by microorganisms. Current work is devoted to investigation of Yarrowia lipolytica proteins responsible for TNT transformation through the pathway leading to ...